Big Hit

300 - Little Daddy Walton & Sons - Automatic Sissy / Funky Soul
301 - Little Daddy Walton & Sons - I’m Leaving / Sitting In With Soul
100/1 - Little Daddy Walton & Sons - Highway Blues / I'm To Blame
102 - Leah Dawson - You Got To Change (Your Evil Ways) / A Good Man (Is All I Want)
103- ?
104 - Johnnie Mae Mathews - Two Sided Thing / You Make Me Feel Good (two different label designs)
105 - Johnnie Mae Matthews - I Have No Choice / That's When It Hurts
106 - Timmy Shaw & Chuck Holiday - You Better (Get Yourself Together) / I'm Such A Lonely Guy - 1968
107 - Barbara Jean & The Lyrics - Why Weren't You There / Any Two Can Play It
108 - Johnnie Mae Matthews - You’re The One / My Momma Didn't Lie
109 - ?
110 - Cynthia & The Imaginary Three - That's What I Am (Without You) / The Many Moods (Of A Man)
110 - Cynthia & The Imaginary Three - That's What I Am (Without You) / Let Your Love (Grow Stronger)
110 - Herbie Thompson - Jungle Time / Let Your Love (Grow Stronger)
110 - Herbie Thompson - Let Your Love (Grow Stronger) Part 1 / Let Your Love (Grow Stronger) Part 2
111 - Johnnie Mae Matthews - Don't Be Discouraged / Don't Be Discouraged
112 - Herbie Thompson - Uncle Tom / Keep On Stepping
112 - Herbie Thompson - Uncle Tom Part 1 / Uncle Tom Part 2
113 - ?
114 - ?
115 - The Eldees - Help Me Grow Up / ?
116 - ?
117 - ?
118 - ?
119 - ?
120 - Lynn Day - I'll Understand / Bit Off More (Then I Can Chew)
121 - ?
122 - ?
123 -  Lynn Day & Black Nasty - Sweet To The Bone / Stop Pussyfootin' Around
124 - ?
125 - Black Nasty - Party On 4^th Street Part 1 / Party On 4^th Street Part 2
126 - ?
127 - ?
128 - ?
129 - Black Nasty - Cut Your Motor Off / Keep On Steppin’
130 - Black Nasty - Freakish Self / Party On Fourth Street
200 - Lynn Day - My Creater / My Creater (Inst)
300 - The Dynamic Walton Brothers - Automatic Sissy / Funky Stuff
301 - Little Daddy Walton & Sons - The Boogie’s Here / Gittin’ It With Soul

Given the way Johnnie Mae Matthews used to switch releases between all her labels it's quite possible that the missing numbers simply weren't released.